Semivolatiles on Rxi-5ms (Split Injection)

	Peaks	tR (min)
1.	1,4-Dioxane-D8 (IS)	1.98
2.	N-Nitrosodimethylamine	2.15
3.	Pyridine	2.18
4.	2-Fluorophenol (SS)	2.87
5.	Phenol-D6 (SS)	3.48
6.	Phenol	3.49
7.	Aniline	3.54
8.	bis-(2-chloroethyl)ether	3.57
9.	2-Chlorophenol	3.62
10.	1,3-Dichlorobenzene	3.74
11.	1,4-Dichlorobenzene-D4 (IS)	3.76
12.	1,4-Dichlorobenzene	3.77
13.	Benzyl Alcohol	3.86
14.	1,2-Dichlorobenzene	3.92
15.	2-Methylphenol	3.95
16.	Bis(2-Chloroisopropyl)ether	3.98
17.	4-Methylphenol	4.06
18.	3-Methylphenol	4.06
19.	N-Nitrosodi-N-propylamine	4.09
20.	Hexachloroethane	4.17
21.	Nitrobenzene-D5 (SS)	4.21
22.	Nitrobenzene	4.22
23.	Isophorone	4.41
24.	2-Nitrophenol	4.49
25.	2,4-Dimethylphenol	4.5
26.	Benzoic acid	4.54
27.	Bis(2-chloroethoxy)methane	4.58
28.	2,4-Dichlorophenol	4.67
29.	1,2,4-Trichlorobenzene	4.76
30.	Naphthalene-D8 (IS)	4.79
31.	Naphthalene	4.81
32.	4-Chloroaniline	4.86
33.	Hexachlorobutadiene	4.96
34.	4-Chloro-3-methylphenol	5.26
35.	2-Methylnaphthalene	5.4
36.	1-Methylnaphthalene	5.49
37.	Hexachlorocyclopentadiene	5.6
38.	2,4,6-Trichlorophenol	5.66
39.	2,4,5-Trichlorophenol	5.69
40.	2-Fluorobiphenyl (SS)	5.73
41.	2-Chloronaphthalene	5.82
42.	2-Nitroaniline	5.93
43.	1,4-Dinitrobenzene	6.02
44.	Dimethyl phthalate	6.11
45.	1,3-Dinitrobenzene	6.12
46.	2,6-Dinitrotoluene	6.17
47.	Acenaphthylene	6.19

	Peaks	tR (min)
48.	1,2-Dinitrobenzene	6.23
49.	3-Nitroaniline	6.29
50.	Acenaphthene-D10 (IS)	6.33
51.	Acenaphthene	6.35
52.	2,4-Dinitrophenol	6.38
53.	4-Nitrophenol	6.42
54.	Dibenzofuran	6.49
55.	2,4-Dinitrotoluene	6.51
56.	2,3,5,6-Tetrachlorophenol	6.59
57.	2,3,4,6-Tetrachlorophenol	6.63
58.	Diethyl Phthalate	6.72
59.	4-Chlorophenyl phenyl ether	6.79
60.	Fluorene	6.8
61.	4-Nitroaniline	6.83
62.	4,6-Dinitro-2-methylphenol	6.87
63.	N-Nitrosodiphenylamine (as Diphenylamine)	6.89
64.	N,N'-Diphenylhydrazine (as Azobenzene)	6.93
65.	2,4,6-Tribromophenol (SS)	7.02
66.	4-Bromophenyl phenyl ether	7.22
67.	Hexachlorobenzene	7.36
68.	Pentachlorophenol	7.51
69.	Phenanthrene-D10 (IS)	7.62
70.	Phenanthrene	7.64
71.	Anthracene	7.68
72.	Carbazole	7.82
73.	di-n-Butyl phthalate	8.16
74.	Fluoranthene	8.73
75.	Benzidine	8.85
76.	Pyrene-D10 (SS)	8.95
77.	Pyrene	8.97
78.	p-Terphenyl-D14 (SS)	9.14
79.	3,3'-Dimethylbenzidine	9.74
80.	Butyl benzyl phthalate	9.79
81.	Bis(2-ethylhexyl) adipate	9.89
82.	3,3'-Dichlorobenzidine	10.6
83.	Benz[a]anthracene	10.62
84.	Chrysene-D12 (IS)	10.65
85.	Chrysene	10.69
86.	Bis(2-ethylhexyl) phthalate	10.8
87.	Di-n-octyl phthalate	12.14
88.	Benzo[b]fluoranthene	12.93
89.	Benzo[k]fluoranthene	12.99
90.	Benzo[a]pyrene	13.77
91.	Perylene-D12 (IS)	13.93
92.	Indeno[1,2,3-cd]pyrene	16.56
93.	Dibenz[a,h]anthracene	16.62
94.	Benzo[ghi]perylene	17

GC_EV1418

Column	Rxi-5ms, 30 m, 0.25 mm ID, 0.25 µm (cat.# 13423)
Sample	Revised SV internal standard mix (cat.# 31886)
	Revised B/N surrogate mix (cat.# 31888)
	Acid surrogate mix (4/89 SOW) (cat.# 31063)
	8270 MegaMix (cat.# 31850)
	8270 Benzidines mix (cat.# 31852)
	Benzoic acid (cat.# 31879)
Diluent:	Dichloromethane
Conc.:	5.0 ng/µL (IS and SS concentrations are 20 ng/µL)
Injection
Inj. Vol.:	1 µL split (split ratio 10:1)
Liner:	Premium 4 mm Precision liner w/wool (cat.# 23305.5)
Inj. Temp.:	275 °C
Oven
Oven Temp.:	50 °C (hold 0.5 min) to 265 °C at 28 °C/min to 285 °C at 3 °C/min to 330 °C at 20 °C/min (hold 5 min)
Carrier Gas	He, constant flow
Flow Rate:	1.44 mL/min
Detector	MS
Mode:	Scan
Scan Program:	Group Start Time (min) Scan Range (amu) Scan Rate (scans/sec) 1 1.5 35-550 5.4
Transfer Line Temp.:	280 °C
Analyzer Type:	Quadrupole
Source Type:	Extractor
Extractor Lens:	9mm ID
Source Temp.:	350 °C
Quad Temp.:	200 °C
Electron Energy:	70 eV
Tune Type:	DFTPP
Ionization Mode:	EI
Instrument	Agilent 7890B GC & 5977A MSD

Download PDF

RELATED CHROMATOGRAM LIBRARY SEARCHES

EPA Method 8270

,

EPA Method 625

,

EPA Method TO-17

Printing tips! To print chromatograms full page, change the print settings in the print dialogue window of your PDF reader software: 1) "fit" or "fit to page", 2) "landscape" for wide chromatograms or "portrait" for tall chromatograms.